Comment on “Chiral Phase Transition in Charge Ordered 1T-TiSe2”. (arXiv:1903.11120v1 [cond-mat.mtrl-sci])
A prior report of the emergence of chirality for the (2x2x2) charge density wave (CDW) in TiSe2 has attracted much interest; the drastic symmetry breaking is highly unusual with few precedents [1]. In that study, key evidence was provided by x-ray diffraction measurements of two superlattice reflections, (1.5 1.5 0.5) and (2.5 1 0). The (2.5 1 0) reflection appeared to show an anomalously large intensity and a transition onset at ~7 K below that of the (1.5 1.5 0.5) reflection. These observations, aided by modeling, were cited as evidence for a separate chiral transition. In this Comment, we show that the prior conclusions based on x-ray diffraction are erroneous. There is just one transition, and it is achiral.
Published in: "arXiv Material Science".