Modulating the electronic and optical properties of monolayer arsenene phases by organic molecular doping

2017-11-15T10:31:47+00:00November 15th, 2017|Categories: Publications|Tags: |

Recently, arsenene monolayer structure of the arsenic with two phases has displayed semiconducting behavior. We have systematically investigated the electronic and optical properties of single-layer arsenene with two types of functionalized organic molecules; an electrophilic molecule [tetracyanoquinodimethane (TCNQ)] and a nucleophilic molecule [tetrathiafulvalene (TTF)], as an electron acceptor and electron donor, respectively. The interfacial charge transfer between the arsenene monolayer and TCNQ/TTF molecules extensively reduces the band gap of arsenene and accordingly resulted in a p- or n-type semiconducting behavior, respectively. We have also performed the interfacial charge transfer from organic molecules to monolayer arsenene and vice versa. The interfacial surface molecular modification has established an efficient way to develop the light harvesting of arsenene in different polarization directions. Our theoretical investigation suggests that such n- and p-type arsen…

Published in: "Nanotechnology".

Tunable electronic and magnetic properties of arsenene nanoribbons

2017-11-08T08:29:02+00:00November 8th, 2017|Categories: Publications|Tags: |

RSC Adv., 2017, 7,51935-51943DOI: 10.1039/C7RA05137A, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lei Ao, Anh Pham, Xia Xiang, Frank Klose, Sean Li, Xiaotao ZuPossible schematic structures of the arsenene nanoribbon.The content of this RSS Feed

Published in: "RSC Advances".

Large magneto-optical effects in hole-doped blue phosphorene and gray arsenene

2017-11-03T14:24:16+00:00November 3rd, 2017|Categories: Publications|Tags: , |

Nanoscale, 2017, Advance ArticleDOI: 10.1039/C7NR05088G, PaperXiaodong Zhou, Wanxiang Feng, Fei Li, Yugui YaoBlue phosphorene (BP) and gray arsenene (GA), consisting of phosphorus and arsenic atoms in two-dimensional (2D) low-buckled honeycomb lattices, respectively, have received great interest because of their excellent electronic and optoelectronic

Published in: "RSC Nanoscale".

Arsenene/Ca(OH)2 van der Waals heterostructure: strain tunable electronic and photocatalytic properties

2017-09-15T12:29:15+00:00September 15th, 2017|Categories: Publications|Tags: , |

RSC Adv., 2017, 7,44394-44400DOI: 10.1039/C7RA08029H, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiao-Hua Li, Bao-Ji Wang, Xiao-Lin Cai, Wei-Yang Yu, Li-Wei Zhang, Guo-Dong Wang, San-Huang KeBased on ab initio calculations, we identify that the arsenene/Ca(OH)2

Published in: "RSC Advances".

Temperature-dependent dielectric functions in atomically thin graphene, silicene, and arsenene

2015-09-01T14:18:56+00:00September 1st, 2015|Categories: Publications|Tags: , , |

The dielectric functions of atomically thin graphene, silicene, and arsenene have been investigated as a function of temperature. With zero energy gap, more carriers in graphene and silicene are thermally excited as temperature increases and intraband transition strengthens, resulting in the strengthened absorption peak. Yet with large energy gap, interband transition dominates optical absorption of arsenene but it reduces as lattice vibration enhances, inducing the redshift and decreased absorption peak. To validate the theoretical method, the calculated optical constants of isolated graphene are compared with ellipsometry results and demonstrate good agreement.

Published in: "Applied Physics Letters".

Hydrogenated arsenenes as planar magnet and Dirac material

2016-10-15T11:36:46+00:00July 13th, 2015|Categories: Publications|Tags: , |

By Shengli Zhang, Yonghong Hu, Ziyu Hu, Bo Cai and Haibo Zeng Arsenene and antimonene are predicted to have 2.49 and 2.28 eV band gaps, which have aroused intense interest in the two-dimensional (2D) semiconductors for nanoelectronic and optoelectronic devices. Here, the hydrogenated arsenenes are reported to be planar magnet and 2D Dirac
…read more

Published in: Applied Physics Letters

Arsenene: Two-dimensional buckled and puckered honeycomb arsenic systems

2016-10-15T12:15:01+00:00February 23rd, 2015|Categories: Publications|Tags: , |

By C. Kamal and Motohiko Ezawa

Author(s): C. Kamal and Motohiko Ezawa

Recently, phosphorene, a monolayer honeycomb structure of black phosphorus, was experimentally manufactured and has attracted rapidly growing interest. Motivated by phosphorene, here we investigate the stability and electronic properties of the honeycomb structure of the arsenic system based on firs…

[Phys. Rev. B 91, 085423] …read more

Published in: Physical Review B

Novel mono-elemental semiconductors: arsenene and antimonene join 2D family

2016-10-15T12:25:50+00:00January 14th, 2015|Categories: News|Tags: , |

Researchers have identified novel 2D wide-band-gap semiconductors with high stabilities, namely monolayer arsenene and antimonene. These materials are indirect wide-band-gap semiconductors, and under strain, they become direct band-gap semiconductors. For arsenene and antimonene, such dramatic transitions of electronic properties could open a new door for nanoscale transistors with high on/off …read more

Via: Nanowerk

Unexpected semiconducting properties in few-layer arsenene. (arXiv:1411.3165v1 [physics.comp-ph])

2016-10-15T12:41:17+00:00November 13th, 2014|Categories: Publications|Tags: , |

By Z. Y. Zhang, D. Z. Yang, D. S. Xue, M. S. Si, G. P. Zhang

We demonstrate few-layer arsenene similar to phosphorene, which are derived
from the or- thorhombic bulk arsenic but are thermally stable, semiconducting
and of high carrier mobility. Although its monolayer is an indirect bandgap
semiconductor, which is dominated by the mutual competition between the
intarlayer bond parameters R1 and R2, the indirect-direct bandgap tran- sition
is …read more

Via:: arXiv Material Science

Arsenene: Two-dimensional buckled and puckered honeycomb arsenic systems. (arXiv:1410.5166v1 [cond-mat.mtrl-sci])

2016-10-15T12:47:14+00:00October 21st, 2014|Categories: Publications|Tags: , |

By C. Kamal, Motohiko Ezawa

Recently phosphorene, monolayer honeycomb structure of black phosphorus, was
experimentally manufactured and attracts rapidly growing interests. Here we
investigate stability and electronic properties of honeycomb structure of
arsenic system based on first principle calculations. Two types of honeycomb
structures, buckled and puckered, are found to be stable. We call them arsenene
as in the case …read more

Via:: arXiv Material Science

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